Orthogonal eigenvectors and Green functions

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SUMMARY

The discussion centers on the orthogonality of eigenvectors associated with discrete and continuous spectra of a Hermitian operator, specifically a Hamiltonian represented as H = H0 + V. The user confirms that eigenvectors ψ (from the continuous spectrum) and χ (from the discrete spectrum) are indeed mutually orthogonal, as demonstrated by an analytical calculation of their inner product, which yielded zero. Initial numerical calculations had suggested otherwise due to an error, which was later rectified.

PREREQUISITES
  • Understanding of Hermitian operators in quantum mechanics
  • Familiarity with eigenvalues and eigenvectors
  • Knowledge of Green's functions, specifically G(z) = 1/(z-H)
  • Experience with perturbative expansions in quantum systems
NEXT STEPS
  • Study the properties of Hermitian operators and their spectra
  • Learn about the calculation and application of Green's functions in quantum mechanics
  • Explore perturbation theory and its implications for eigenvalue problems
  • Investigate numerical methods for calculating inner products of eigenvectors
USEFUL FOR

Quantum physicists, mathematicians, and students studying spectral theory and quantum mechanics, particularly those working with Hermitian operators and Green functions.

paolorossi
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Hi you all. I have to diagonalize a hermitian operator (hamiltonian), that has both discrete and continuous spectrum. If ψ is an eigenvector with eigenvalue in the continuous spectrum, and χ is an eigenvector with eigenvalue in the discrete spectrum, is correct to say that ψ and χ are always mutually orthogonal? I think the answer is yes. But if I numerically calculate the inner product between ψ and χ, then I find that this is far from zero.

PS
I work in this way.
I calculate the eigenvalues and eigenvectors from the Green operator.
Specifically, I have the hamiltonian operator

H = H0 + V

H0 has only continuous spectrum. Using a perturbative expansion, I find the Green operator

G(z) = 1/(z-H)

in terms of V and of the Green operator of H0

G0(z) = 1/(z-H0)

So I find that G(z) has a branch cut and one simple pole. This is consistent with various works and books. Then I calculate the eigenvalues and the corrispondent eigenvectors. So I express ψ and χ in terms of a common basis, and using the Fourier coefficients I can calculate the inner product.
 
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ok I solve it. I have calculated analytically the inner product and I see that it is zero. In fact, I had made ​​a mistake in the numerical calculation.
 

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