Principle and Angular Momentum Quantum Numbers

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The discussion centers on the understanding of quantum numbers, particularly the angular momentum quantum number and the principal quantum number. The principal quantum number (n) determines the size of an electron's orbital, with higher values indicating greater distances from the nucleus and larger orbital sizes. The 2s and 3s orbitals differ in radius but share the same shape. Additionally, it is clarified that all orbitals, including s and p, can overlap, and while the density of the wave function varies across regions, it is never zero, meaning electrons occupy all available space around the nucleus. The conversation emphasizes the complexity of visualizing quantum numbers and the nature of electron distribution in atomic orbitals.
henry3369
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My understanding of the angular momentum quantum number is that a different number indicates a different region of space that the electron can occupy. So does the principle quantum number determine the size of that region? For example, is 2s the same as 3s in shape, but the 3s has a greater radius? Also can different orbitals such as the s and p orbitals overlap? If so, would the energy levels in the overlapping regions be the same? I'm having a hard time picturing the meaning of the quantum numbers.
 
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n, designates the principal electron shell i,e distance of the electrons from the nucleus, the larger the number n is, the farther the electrons are from the nucleus, the larger the size of the orbital, and the larger the atom is
 
All orbitals overlap, you can't say

henry3369 said:
different number indicates a different region of space that the electron can occupy

as that's simply not true. Technically every electron occupies all the space around the nucleus. The density of the wave function in different regions differ, but it is (almost) never zero.
 
I came.across a headline and read some of the article, so I was curious. Scientists discover that gold is a 'reactive metal' by accidentally creating a new material in the lab https://www.earth.com/news/discovery-that-gold-is-reactive-metal-by-creating-gold-hydride-in-lab-experiment/ From SLAC - A SLAC team unexpectedly formed gold hydride in an experiment that could pave the way for studying materials under extreme conditions like those found inside certain planets and stars undergoing...

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