Properties of derivatives of a wavefunction?

In summary, the conversation discusses a problem related to the derivative of a wavefunction and its behavior at boundaries. The person is seeking help in understanding the concept and mentions finding two solutions that claim the derivative of the wavefunction should approach zero at infinity. They also mention that Griffiths' book states the wavefunction should approach zero at boundaries but does not mention anything about the derivatives.
  • #1
Torboll1
1
0
Hi!

I'm currently re-reading Griffiths introductory QM book and plan to do most of the exercises. I got stuck on one problem and had to look for some hints and found two solutions that both claim that:

[tex] \int_{-\infty} ^{\infty} \frac{\partial }{\partial x}\left[ \frac{\partial \Psi ^{*}}{\partial x} \frac{\partial \Psi}{\partial x} - \Psi ^{*} \frac{\partial ^2 \Psi }{\partial x^2} \right] dx = 0 .[/tex]

What Griffiths really push is that the wave function approaches zero at the boundaries but he states nothing about the derivatives (other than that they need be continuous). Can someone help me understand this?
 
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  • #2
The derivative of a wavefunction out to infinity should approach zero as well. This is the same as in, say, an infinite well, where the wavefunction must be zero at the well wall. For the derivative of the wavefunction to also be continuous at the boundary, it must approach zero smoothly.
 

1. What is a wavefunction?

A wavefunction is a mathematical description of the quantum state of a particle or system. It represents the probability amplitude of finding a particle in a particular position or state.

2. How are derivatives of a wavefunction calculated?

The derivatives of a wavefunction are calculated using mathematical operators known as the momentum and position operators. These operators act on the wavefunction to determine its rate of change in space and time.

3. What are the physical properties of derivatives of a wavefunction?

The physical properties of derivatives of a wavefunction include the momentum and position of a particle or system, as well as its kinetic energy and probability density. These properties can provide important information about the behavior and interactions of particles at the quantum level.

4. What is the significance of derivatives of a wavefunction?

Derivatives of a wavefunction play a crucial role in understanding the behavior of particles at the quantum level. They help us to calculate important physical quantities, such as energy and momentum, and provide insights into the probabilistic nature of quantum mechanics.

5. How do derivatives of a wavefunction relate to the Schrödinger equation?

The Schrödinger equation is a fundamental equation in quantum mechanics that describes the time evolution of a wavefunction. Derivatives of the wavefunction, such as the first and second derivatives, are used in the Schrödinger equation to describe the behavior of particles over time.

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