Quantum Mechanic. penetration distance and probability Density

AI Thread Summary
The discussion focuses on calculating the distance beyond the surface of metallic sodium where an electron's probability density is 20% of its value at the surface. The work function of sodium is given as 2.7 eV, and the relevant equations involve the penetration depth (η) and the wave function (ψ). The user successfully calculated η to be approximately 1.19 x 10^-10 m and derived the distance using the probability density condition. The final result indicates that the distance is 0.805η, equating to about 0.096 nm. The user confirms that their method and answer are correct.
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Homework Statement



Assume that a typical electron in a piece of metallic sodium has energy - E_{0} compared to a free electron, where E_{0} is the 2.7 eV work function of sodium.

At what distance beyond the surface of the metal is the electron's probability density 20% of its value at the surface?

Homework Equations



η=\frac{\hbar}{\sqrt{2m( U_{0} - E)}}

ψ_{(x)}=ψ_{edge} e^{-(x-L)/η}

The Attempt at a Solution



I've assumed the surface of the sodium metal is the barrier. I have also assumed U_{0}-E= 2.7eVGiven that the probability density must be 20% at a distance from the surface I've used the following method to get my answer and want to check if my assumptions/work are correct.

I've worked η≈1.19*10^{-10}m

Because I need probability density to be 20% of what it would be at the barrier I've done the following;

0.2=|ψ|^{2}

ψ_{(x)}=ψ_{edge} e^{-(x-L)/η} ∴ |ψ_{(x)}|^{2}=(ψ_{edge} e^{-(x-L)/η})^{2}

\sqrt{0.2}=ψ_{edge} e^{-(x-L)/η}

Given x value is going to be x value of barrier + zη

0.447=ψ_{edge} e^{-(zη)/η}

ln 0.447 =ψ_{edge} -(zη)/η

-0.805=ψ_{edge} -(zη)/η

-0.805=-z

z=0.805

Would the answer be 0.805η (0.096 nm)

Any help would be greatly appreciated :)
 
Last edited:
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Problem is now solved, the answer and method was correct
 
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