Car tires can generate static electricity due to friction with the road as the vehicle moves, leading to the accumulation of electrons on the tire's surface. This process results in the formation of ions, which contribute to static charge. While this phenomenon occurs, it is often not the primary cause of static shocks experienced when exiting a vehicle; instead, the vehicle's seat fabric is usually the main culprit. For further understanding, resources like triboelectrification charts and educational videos on electricity principles can be helpful. Overall, the interaction between tires and the road does play a role in static electricity generation.