Placing a hand behind glass does not allow it to feel radiant heat from a fireplace because glass is transparent to visible light but blocks infrared radiation, which carries heat. This phenomenon contrasts with sunlight, where glass allows infrared radiation to pass through, enabling heat sensation. The discussion highlights the greenhouse effect, where barriers like glass trap heat by allowing visible light in while preventing infrared radiation from escaping. This principle explains why energy enters during the day and is retained at night, leading to a temperature increase. Understanding these radiation spectra differences is crucial for grasping the relationship between heat transfer and the greenhouse effect.