Reading a Binary Phase Diagram (lever rule etc.)

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SUMMARY

The discussion focuses on analyzing a binary phase diagram with a composition of 20WT% A and 80WT% B. The first solid appears at approximately 820°C, identified as the β phase with a composition of about 94%B and 6%A. Just below the eutectic temperature, the phases present are α and β, with compositions of 91%B and 9%A. The weight fractions of these phases are calculated using the lever rule, resulting in 22.9% β and 78% α, with their respective compositions being 22.9B/77.1A for β and 78%A/22%B for α.

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  • Understanding of binary phase diagrams
  • Knowledge of the lever rule in phase equilibrium
  • Familiarity with eutectic systems
  • Basic thermodynamics related to phase transitions
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  • Study the application of the lever rule in different phase diagrams
  • Learn about eutectic points and their significance in material science
  • Examine the cooling curves of binary alloys
  • Research the properties and applications of α and β phases in metallurgy
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cookiemnstr510510
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Hello All,
Wanted to see if I am approaching this problem correctly, I have an exam coming up and am pretty sure something like this will show up.

Examine the phase diagram (phase.jpg) with a 20WT% A and 80WT%B which is allowed to cool slowly from liquid

A) what temp does the first solid appear?
B)What phase it is?
C)what is its composition?
D)What phases are present just below the eutectic temperature?
E) What are the compositions of these phases?
F) What are the weight fractions of these phases?

My attempt:

A) From the graph I would say about 820°C
B) The first solid is β phase (since the only things are L+β)
C)The composition is about 94%B and 6%A
D) The phases present just below the eutectic are α+β
E) 91%B and 9%A
F) This is where you have to use the lever rule:
For β phase:
wt%=##\frac{91-72}{91-9}##*100%=22.9%B
The composition of β: 22.9B and 77.1A

For α phase:
wt%=##\frac{72-8}{91-9}##*100%=78%A
The composition of α: 78%A and 22%B

Thanks in advanced!
 

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A) To my eye, nearer 840 or 850, but just an estimate.
B) - D) OK
E) Question asks for composition of both phases.
F) The axis about which the lever pivots is not the eutectic composition, but the overall composition of the mixture. (Test your answer: if you have x% α with composition 8% B, and y% β with composition 91% B, do you have 80% B overall?)
 
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