Regarding quantum physics(fermi energy)

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Homework Help Overview

The discussion revolves around deriving expressions related to the pressure and bulk modulus of an electron gas in the context of quantum physics, specifically focusing on Fermi energy and its relationship with energy, volume, and pressure.

Discussion Character

  • Exploratory, Mathematical reasoning, Problem interpretation

Approaches and Questions Raised

  • Participants discuss the relationship between average electron energy, Fermi energy, and pressure, questioning how to express pressure in terms of internal energy (U) and volume (V). There are attempts to substitute variables and simplify equations, with some participants unsure about the correct substitutions and derivatives needed.

Discussion Status

Participants are actively exploring different approaches to derive the pressure and bulk modulus in terms of U. Some guidance has been offered regarding substitutions and derivatives, but there remains uncertainty about how to express the final results solely in terms of U.

Contextual Notes

There is a focus on ensuring that the derived expressions adhere to the constraints of the problem, specifically the requirement to express the bulk modulus in terms of U only. Participants are also reminded that U depends on V, which complicates the derivation.

lotrsimp12345
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The average electron energy in an electron gas is known to be <e>=3E(f)/5. The energy for N such electrons would be 3NE(f)/5. Find the pressure in terms of U and V, where V is the volume of the electron gas.

My solution.

Fermi energy
E(f)=(h^2/2m)*((3N/8*pie*V)^(2/3))
therefore E(F) is proportional to V^(-2/3)
since it is proportional i just have to plug into 3NE(f)/5 or the other one correct?

Thanks.




so which formula do i plug V^(-2/3) into E(F)? The 3NE(f)/5 or 3E(f)/5.
 
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Hah, you have me confused. Let's write down what you have:

U=(3/5)NE_F
and
E_F = C V^{-2/3}

where I stuck all those nasty constants that don't depend on V in the term C.

So, you also know P=-dU/dV.

You have all the pieces, just put them together now.
 
but the pressure needs to be in terms of U and V.
 
First use substitution to remove the Fermi energy from the first equation. Then take the derivative with respect to V. And substitute back in U to get the pressure in terms of U and V.
 
thanks.
 
after i take derivative i have p=-dU/dV=(6/15)NC*(V^(-5/3))
you can't substitue this into U because it isn't=U to derivative of du/dv.
 
First, 6/15 can be simplified. Second, you can pull a U out of that final equation of yours. Just remember what U is equal to, and factor that out of the equation above, and then make it U.
 
Can i do this U=3/5*N*C*(V^(-2/3)). so solve for N and plug into p=-dU/dV=(6/15)NC*(V^(-5/3))? don't really understand what you mean by pull out U from -du/dv.
 
You can do that as well, or even solve for C and plug it in. All the constants will cancel out in the end and you will be left with U and V for your pressure equation.
 
  • #10
thank you so much.
 
  • #11
now he asks to find bulk modulus. B=-V*(dp/dv) but he wants it in terms on U only and if i take derivative and simplify i am left with 2U/3V again but am unsure of how to get further in terms of plugging in for V.
 
  • #12
You need to show some work. And remember that U also depends on V.
 
  • #13
so use U=(3/5*N*C*V^(-2/3)) solve for V and substitute?
 
  • #14
here's what i did B=-V(dp/dv)=-V((d/dV(2U/3V))=2U/3V. But i need my answer in terms of of only U.
 
  • #15
You didn't take the derivative of U with respect to V in that formula. But that formula may not be the best to take the derivative of. Try a formula you quoted earlier...

p=-dU/dV=(6/15)NC*(V^(-5/3))?

Take the derivative of that pressure with respect to volume, then substitute the U back in.

Edit: Nevermind, I see your problem. What does the problem ask for exactly?
 
Last edited:
  • #16
Problem:
The bulk modulus, B, is defined to be B=-V(dp/dv). Find expression of B in terms of U.
 
  • #17
Well, I get a similar answer as with the U/V, except I get a different coefficient than you. But I still also get the volume in my bulk modulus. So not sure how to express it only as U.
 
  • #18
thanks for help i will just ask teacher tom.
 

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