Resonant Structure of Nitrate Ion in AgNO3: Draw a Possible Solution

AI Thread Summary
The discussion focuses on drawing a resonant structure of the nitrate ion in AgNO3. Participants clarify that the question specifically asks for the nitrate ion's structure, which is independent of the counterion. A key point raised is the importance of having the correct number of valence electrons for nitrogen, which should be eight, not twelve. The concept of localized versus delocalized charges in resonant structures is also explained, emphasizing that while individual structures have localized charges, the rapid switching between them results in an observable delocalized charge. Overall, the conversation highlights the need for accurate Lewis dot diagrams to represent the nitrate ion's resonant structures.
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Homework Statement


Draw at least one resonant structure of the nitrate ion in AgNO_{3}.



The Attempt at a Solution


Is this a possible resonant structure of the nitrate ion?

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You want a Lewis Dot Structure of AgNO3, not just NO3-.
 
I don't think so - question asks for structure of nitrate ion, and in general structure of nitrate ion doesn't depend on the counterion.

temaire: resonant structure should have localized charge. How many valence electrons on N?

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I think I see where I went wrong. My diagram has 12 valence electrons for N, while I'm supposed to have only 8. But how do resonant structures have localized charges? Shouldn't they have delocalized charges?
 
No, delocalized charge is effect of switching between resonant strutures. Charge is localized in any individual structure, but as molecule switches between them very fast, what we observe is charge that is delocalized.

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So, if I was asked to come up with a resonant structure for the nitrate ion, I would have to include all of the possible lewis dot diagrams for nitrate ions with a certain number of single or double bonds?
 
Yes, indeed.
 

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