The diffracted wave contains a different k spectrum because it now contains spatial information about the object that caused it to diffract. Smaller objects (or more correctly, their aperture function along a specific direction) contain more spatial frequency components in that direction, and thus result in a diffracted wave possessing a wider k spectrum.
Since we usually speak of a monochromatic incident wave, the magnitude of k remains constant, thus a change in the components of k imply a change in direction of the wave.
Claude.