That's what I thought at first too. The reason it's not is as follows: The diagonal is the line segment that cuts right through the centre of a cube between opposite corners. In a 3D coordinate system this is the line segment from the point (0,0,0) to the point (1,1,1). To find the nature of this line we can proceed as follows:
First consider the line segment from (0,0,0) to (1,1,0), which runs diagonally along the base of the cube. This is the hypotenuse of a 45 degree right-angled triangle, and has length ##\sqrt 2##, by Pythagoras' Theorem. That's where the 45 degrees, that we expected, comes in.
Now the red rod is the hypotenuse of the right-angled triangle whose base is the segment (0,0,0)-(1,1,0) and whose vertical side is the segment (1,1,0)-(1,1,1). This is a right-angled triangle with adjacent and opposite sides of length ##\sqrt 2## and ##1##. Hence by Pythagoras the hypotenuse has length ##\sqrt{(\sqrt 2)^2+1^2}=\sqrt 3## and whose angle between the horizontal line (0,0,0)-(1,1,0) and the hypotenuse (0,0,0)-(1,1,1) has tangent ##1/\sqrt 2##. So that angle is ##\tan^{-1}\left(1/\sqrt 2\right)=35.3^\circ##.
Note that this is not the angle to any of the original three rods. It is the angle to the horizontal plane. The angle to each of the rods is the 90 degrees minus that, which is about 55 degrees. To see that, note that the line (1,1,0)-(1,1,1) is the adjacent side of the triangle and is also parallel to the vertical axis. The angle of the red rod to that adjacent side is 90 deg minus the 35 deg angle to the plane. By the parallelism we just noted, that must also be the angle the red rod makes with the vertical axis. Since the problem is symmetrical between the three original axes, we conclude that that must also be the angle the red rod makes with each of the other two axes.