Solving Part B of PV=NkbT: An Explanation

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Homework Statement



"see attachment"

Homework Equations



PV=NkbT
Change in entropy = Boltzmann Constant x In(Macrostate)

The Attempt at a Solution



for part A, I knew that PV=NKbT

giving that pressure is 101300Pa volume is 1*10^-3 m^3, Kb is 1.38*10^-23 and T=300K
I find N to be 2.446*10^22 atoms


the problem I have is with part B

the question states that microstate is proportion to V^N where N is the number of atom I found in part A, and V is the volume which is 1*10-9 m^3. Thus V^N is a very small number which is pretty much zero. Change in entropy = Boltzmann Constant x In(Macrostate), since Macrostate is zero, there is an error in this calculation. Since In(0) is undefined. What am I suppose to do in this question??
 
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I forgot to attach the question, here it is
 

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Hi Junkwisch!

Always in physics things are only big or small relative to other things. The numerical value of V^N depends entirely on what units you're using.

Perhaps you can simplify \ln\left(V^N\right) without making an approximation? :smile:
 
Junkwisch said:
Change in entropy = Boltzmann Constant x In(Macrostate)
You should check that you have the correct relationship here. How can the left side of the equation be a change when there's no corresponding change present on the righthand side of the equation? Also, what is "Macrostate" supposed to represent?
 
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