To find volume using the ideal gas law PV=nRT, the discussion centers on the values for pressure (P), number of moles (n), the gas constant (R), and temperature (T). The user initially calculated volume using pressure in Pascals but later switched to atmospheres, leading to confusion over the correct volume. The correct calculation with R expressed in liter-atm/mol K yields a significantly large volume of approximately 118.64 liters for 5.3 moles of gas at standard temperature and pressure. Participants emphasize the importance of unit consistency throughout the calculations. The final volume indicates the substantial size required to contain the specified amount of gas.