With what? You were just told that the solution you give is correct.
The way I would approach this problem is:
First draw a picture: a unit circle on a pair of axes.
You are told that theta lies between 3pi/2 and 2 pi and you should know (MEMORIZE) that the axes correspond to 0 (at (1,0), pi/2 (at (0,1), pi (at (-1,0), 3pi/2 (at (0,-1) (and 2pi again at (1,0)). This is a circle with radius 1, diameter 2, and so circumference 2pi- those numbers just measure the distance around the circle.
Theta is between 3pi/2 and 2pi so you should mark a point on the circle between (0,-1) and (1,0) (i.e. in the fourth quadrant as dextercioby originally said). Since points on the unit circle have coordinates (cos(theta), sin(theta)), knowing that sin(theta)= -4/7 tells you that y= -4/7. The equation of the circle is x2+ y2= 1 so you must have x2+ 16/49= 1= 49/49 . That is:
x2= 33/49 and so x= cos(theta)= +√(33)/7 (positive root because x is positive in the fourth quadrant).
Now that you know both sin(theta) and cos(theta) you know that 1/cos(theta)= tan(theta)= sin(theta)/cos(theta)= (-4/7)(7/sqrt(33))= -4/sqrt(33).
As for "where do I use sin^2(x)+ cos^2(x)= 1?", you don't HAVE to use it directly.. I basically used it when I wrote the equation of the circle, x2+ y2= 1, which, since x= cos(theta) and y= sin(theta), is the same thing.