Specific heat of solid of one dimensional quartic oscillators

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SUMMARY

The discussion focuses on calculating the heat capacity of a system of N weakly interacting particles performing one-dimensional oscillations, where the restoring force is proportional to x^3. The energy of one oscillator is defined as E = p^2 / 2M + qx^4 / 4, and the partition function Z is derived from the integrals of the exponential of the energy terms. The challenge lies in evaluating the integral of exp(-x^4), which is essential for determining the partition function and subsequently the heat capacity Cv = N d/dT (average E).

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  • Knowledge of integrals involving exponential functions
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  • Learn how to evaluate integrals of the form exp(-x^4) using advanced mathematical techniques
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Homework Statement



A system consists of N very weakly interacting particles at temperature T sufficiently high so that classical stat mech is applicable. Each particle has mass M and is free to perform one dimensional oscillations about its equilibrium position. Calculate the heat capacity of this system of particles if the restoring force is proportional to x^3.


Homework Equations



spring constant = q
energy of one oscillator E = p^2 / 2m + qx^4 / 4

partition function: Z = integral ( exp(-BE ) dx dp
both integrals from -inf to +inf

where B = 1/kT

The Attempt at a Solution



Cv = N d/dT (average E)

average E = - d / dB [ ln Z ]
Z = integral [exp (-Bp^2/2m) dp ] * integral [exp (-Bqx^4/4) dx ]

the first integral is simply sqrt(pi * 2m / B )
I have no idea how to find the integral of exp(-x^4), so I can't find this partition function.
 
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Try the substitution t=\frac{\beta q x^4}{4} and make use of the gamma function:

\Gamma(z)\equiv \int_0^\infty t^{z-1}e^{-t}dt
 

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