hansbahia said:
Total Charge on a sphere 4/3πr^3ρ
p is volume charge density in that equation. That would be the total charge of the sphere if charge was uniformly distributed throughout the sphere.
But we are dealing with an electrostatics problem and we know conductors can't have fields inside them so from Gauss's Law, any charge on that inner sphere must be on the surface. The total charge of the sphere is 4*pi*r^2*ps (ps is charge per unit area on the surface).
If the problem had the charged spherical charge sheet enclosing nothing, the E field inside would be zero (Gauss's Law). If the problem had the spherical charge sheet surrounding an isolated and concentric spherical conductor (almost this problem), the fields inside would be zero (Gauss's Law again).
But now we are grounding that inner spherical conductor. Gauss's Law can no longer be conveniently used because a net charge (supplied by the earth) can appear on the inner conductor. In the last scenario, we could say the net charge on that conductor was zero because it was neutral. And in this scenario we have no idea what that net charge might be so the solution has to be found another way.
Instead think of it this way: you know from symmetry that the charge that accumulates on the inner conductor will be uniformly distributed on its surface and just under the surface (inside the conductor) the voltage is zero. So find the voltage just under the surface by adding the voltage due to the charge on the outer sphere to the voltage due to the charge on the inner sphere. They have to add to zero.
Here's a hint: consider each charged sphere separately, apply Gauss's Law to see that the field inside the sphere is zero (not the voltage though!). This means you can calculate the voltage at, say, the centre of the sphere and you will know the voltage everywhere inside that sphere is the same.
You can justify adding the separate spherical sheet charges together to form your scenario by appealing to the linearity of the E field (the field due to two point charges is the sum of the fields due to each point charge separately). In using this step, the charges on each sphere must not move when they are brought together!