The discussion centers on the Spin Quantum Number of electrons, which is always +1/2 or -1/2 due to their classification as fermions, possessing intrinsic spin characteristics. The value of 1/2 is fundamental to electron behavior and is linked to the outcomes observed in experiments like the Stern-Gerlach experiment, where electrons exhibit two distinct spin states. While resources like Hyperphysics provide insights into electron behavior, they do not explain why the spin is specifically ±1/2. The concept of spin angular momentum is analogous to orbital angular momentum, with the spin value emerging from theoretical derivations that are complex and not typically covered in basic courses. The discussion emphasizes that the intrinsic nature of electrons dictates this spin value, reinforcing the idea that it is a fundamental characteristic of these particles.