sirchasm said:
Well, thermodynamic entropy is equivalent to Shannon entropy, when you set k to 1.
Then heat has the same units as information, then heat = information in (0,1) basis.
Yes there are a few different issues I see here. First is that some entropies like Gibbs, is constructed from a probability space. Boltzmanns, are constructed instead from a combinatorial approach if microstates. It effectively constructs a kind of discrete probability space.
The microstructure in physical systems, are the possible microstates a system can have, various degress of freedom. But aside that, the other major difference between the physical entropies is like you note boltzmanns constant.
When relating these measures, what is the conceptual meaning of boltzmanns constant?
As I see it, it's meaning becomes obvious only when you put the entropy measure in a larger context. For example, why do we need a measure of disorder in the first place? Well, it's because it helps us figure out what more, or less probable. Ultimately, probabilities are linked to probabilities. There are also entropies (like the relative KL entropy) that relate to transition probabilities.
If you play with these expressions, the constant in place of boltzmanns, typically represents a total "mass" of the probability distribution. Ie. it scales the weight of the entire measure itself. I.e it's a kind of measure of measure.
This is where I think it gets more interesting, and it relates to probabilities in the sense that the probability of something "specifically-unlikely" still depends on the total confidence _in hte measure itself_, which is pretty much the function of boltzmanns constnat IMHO.
This can be exploited also when you consider dynamical, and competing microstructures or probabiltiy spaces, then the constant in front, is a weight between the structures.
So the full relevance of boltzmanns constant enters the picture first when then entropy measure is used in probability calculations, or the measures is leveled against alternative measures of disorder.
/Fredrik