Interesting question!
It seems true. Maybe you could prove it using induction?
The base cases could be integers from 1 to 20, say, by just showing the sums.
Then you could assume that it works for all composite numbers up to a composite number k.
Then does it work for the next composite number? Well, look at the largest prime number less than it. If composite - prime is not 1 or 4 or 6, then the sum can certainly be expressed as prime + (sum for the difference composite - prime, which can definitely be done... if the difference is prime, just take the prime, otherwise, the inductive hypothesis covers it). If the difference is 1 or 4 or 6, try the next prime number below the one you just tried. If this isn't 4 or 6, do the same thing. If it is, try the next lower prime number. And etc.
21 = composite, 19 = prime, diff = 2, done with sum = 19 + 2.
22 = composite, 19 = prime, diff = 3, done with sum = 19 + 3.
24 = composite, 23 = prime, diff = 1. Try 19 = prime, then diff = 5 and done with 19 + 5.
25 = composite, 23 = prime, diff = 2, done with 23 + 2.
26 = composite, 23 = prime, diff = 3, done with 23 + 3.
27 = composite, 23 = prime, diff = 4, try 19 = prime, diff = 9, done with 19 + psum(9) = 19 + 7 + 2.
etc.
This is just a sketch, but I think it should work. Does anybody have any comments?