The ALPHA experiment implies that if there’s any fractional difference between the transition frequencies of hydrogen and antihydrogen, it’s less than ##2 × 10^{−10}##. In a way, that null result is reassuring. The symmetry between particles and their antiparticles is underpinned by the theories of both quantum mechanics and general relativity, so any observed difference between matter and antimatter spectra would require major changes to most of what we think we know about the laws of physics.
The nature of those changes remains to be seen. “In the search for a new effect, it’s useful to identify all possible types of signals, and indeed a general theory of all possible signals exists,” says Alan Kostelecky of Indiana University Bloomington. “But until an effect is discovered, predictions from specific models shouldn’t be taken too seriously.”
Still, it’s possible to make some educated guesses about what a matter– antimatter difference might look like. Because the revamping of quantum mechanics and general relativity could lead to unification of the two theories, one might expect the telltale spectroscopic difference to be on the natural size scale for unification effects: the ratio of the energy of electroweak processes to the Planck energy, or somewhere between ##10^{−17}## and ##10^{−23}##. It’s conceivable that spectroscopic measurements could eventually chip away at that range. But that would require progress not just in antihydrogen spectroscopy but also in hydrogen spectroscopy. The latter’s precision is currently around ##10^{−15}##.