The Eigenfunction of a 2-electron system

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Settho
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Homework Statement
Show that the wave function is an eigenfunction of the hamiltonian.
Relevant Equations
Hamiltonian, wave function, energy and Born radius
Hello!

I am stuck at the following question:
Show that the wave function is an eigenfunction of the Hamiltonian if the two electrons do not interact, where the Hamiltonian is given as;
Equation for the sum of two one-electron Hamiltonians: H1 + H2 = -(ħ²/2m_e)∇₁² - Ze²/(4πε₀r₁) - (ħ²/2m_e)∇₂² - Ze²/(4πε₀r₂).


the wave function and given as;
Hydrogen-like 1s wave function ψ1s(r,θ,φ) = (1/√π)(Z/a0)^(3/2) e^(-Zr/a0), written as an equation.


and the energy and Born radius are given as:
Equation: E1s = -(me e^4)/(32 pi^2 eps0^2 hbar^2) Z^2 = -(e^2)/(8 pi eps0 a0) Z^2, where a0 = 4 pi eps0 hbar^2/(me e^2).


and I used this for ∇ squared:
Radial part of the Laplacian in spherical coordinates: (1/r^2) d/dr (r^2 d/dr), written as a fraction and derivatives.


I am stuck at the end of the calculation. I know Z = 2, but somehow I don't end up with the energy, which you need to show that it is indeed an eigenfunction. This is what I get and where I am stuck at:
Equation for energy E equals negative h-bar squared over 2m, times the bracketed sum of (negative 4 over a0 r1), plus (4 over a0 squared), minus (2e squared over 4 pi epsilon0 r1), all multiplied by psi.


and even when I substitute a0 in this formula, I don't get the energy value. I honestly don't know where it did go wrong.
If someone is able to help, that would be great.
 
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You need to substitute the two-electron wavefunction$$\psi(r_1,r_2)=\psi(r_1)\psi(r_2)=\frac{1}{\sqrt{\pi}}\left( \frac{Z}{a_0}\right)^{3/2}e^{-\frac{Z}{a_0}r_1}\frac{1}{\sqrt{\pi}}\left( \frac{Z}{a_0}\right)^{3/2}e^{-\frac{Z}{a_0}r_2}$$in your Hamiltonian. The energy is a constant and should have no ##r## dependence.
 
Last edited:
But isn't it just the idea to split the Hamiltonian in electron 1 and electron 2 instead of the two-electron wave function?
 
Settho said:
I am stuck at the end of the calculation. I know Z = 2, but somehow I don't end up with the energy, which you need to show that it is indeed an eigenfunction. This is what I get and where I am stuck at:
View attachment 242595
The ##-\hbar^2 / 2m## term doesn't factor out of all terms.
 
DrClaude said:
The ##-\hbar^2 / 2m## term doesn't factor out of all terms.

Your simple suggestion made me solve the problem. Thank you so much!