The Mysteries of Simple Equalities in Thermodynamics

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The discussion centers on the application of thermodynamic equalities, specifically ΔH = CpΔT and ΔU = CvΔT, and their usage under different conditions. It raises a question about the validity of using these equations during gas compression and expansion, particularly regarding constant pressure assumptions. Participants clarify that ΔH is typically applicable at constant pressure, while ΔU is relevant for constant volume scenarios. Additionally, the distinction between δf and df is explained, with δf representing a finite change and df denoting an infinitesimal change. Understanding these concepts is crucial for grasping thermodynamic principles.
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This is an important concept of thermodynamics,that I'm having some trouble understanding.

My question is, when can we use these equalities?

\Delta H=C_{p}\Delta T

and

\Delta U=C_{v}\Delta T

For instance, I thought the first one could only be used when the pressure of the system is constant, but I've seen it being used on compression and expansion of gases.

Does anyone know?

Thanks in advance!

By the way, there's this little thing i don't know too. What's the difference between writing

\delta f=... and df=...

meaning both derivative of "f"
 
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An1MuS said:
This is an important concept of thermodynamics,that I'm having some trouble understanding.

My question is, when can we use these equalities?

\Delta H=C_{p}\Delta T

and

\Delta U=C_{v}\Delta T

For instance, I thought the first one could only be used when the pressure of the system is constant, but I've seen it being used on compression and expansion of gases.

Does anyone know?

Thanks in advance!

By the way, there's this little thing i don't know too. What's the difference between writing

\delta f=... and df=...

meaning both derivative of "f"
\delta f=... is some finite change in the function. such as evaluating f(1) then f(1.1)

df=... is an infinitesimal change in the function.

i.e. the limit as this change goes to 0.
 
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