Thermodynamics: Gibs free energy

AI Thread Summary
The discussion focuses on calculating the standard Gibbs free energy of formation for water vapor at 25°C using the equation ΔG = ΔH - TΔS. The user initially calculated ΔG as -457 kJ/mol but later realized this value corresponds to the formation of 2 moles of water. To find the standard Gibbs free energy per mole, the user acknowledges the need to divide the initial result by 2, leading to the correct answer of -227 kJ/mol. This highlights the importance of considering stoichiometry in thermodynamic calculations. The conversation emphasizes clarity in unit conversions and the significance of understanding the reaction's mole ratio.
ortegavs
Messages
13
Reaction score
0

Homework Statement


What is the standard Gibbs free energy of formation of water vapor at 25 C, if , for the reaction shown below under standard conditions, Δ H = -484 KJ/mol and ΔS= -89 J/mol K?
2H2(g) + O2(g) >>> 2H2O(g)

Homework Equations



ΔG = ΔH - TΔS


The Attempt at a Solution

I converted 25 C to kelvin. I then simply plugged in the values. -484000J/mol -(298K(-89J/mol k)) I get -457 kJ/mol. Answer provided is -227. I don't understand how they got this number.
 
Physics news on Phys.org
I think I understand. The answer that I provided is for the equation which has 2 mols of water. The correct answer is kJ/mol not per 2mols so I have to divide by 2 to get the correct answer. Can someone back me up on this?
 
Thread 'Collision of a bullet on a rod-string system: query'
In this question, I have a question. I am NOT trying to solve it, but it is just a conceptual question. Consider the point on the rod, which connects the string and the rod. My question: just before and after the collision, is ANGULAR momentum CONSERVED about this point? Lets call the point which connects the string and rod as P. Why am I asking this? : it is clear from the scenario that the point of concern, which connects the string and the rod, moves in a circular path due to the string...
Thread 'A cylinder connected to a hanged mass'
Let's declare that for the cylinder, mass = M = 10 kg Radius = R = 4 m For the wall and the floor, Friction coeff = ##\mu## = 0.5 For the hanging mass, mass = m = 11 kg First, we divide the force according to their respective plane (x and y thing, correct me if I'm wrong) and according to which, cylinder or the hanging mass, they're working on. Force on the hanging mass $$mg - T = ma$$ Force(Cylinder) on y $$N_f + f_w - Mg = 0$$ Force(Cylinder) on x $$T + f_f - N_w = Ma$$ There's also...
Back
Top