You can see that if you look at the graph of the sine function.
The usual way to solve these equations, however, is by looking at the unit circle.
See http://en.wikipedia.org/wiki/Unit_circle" .
On the unit circle you can see that there are 2 angles, where sine takes on the same value.
That is, for a small angle t, the sine of phi is the y-value on the right side of the unit circle belonging to this angle t.
But on the left side of the unit circle there is a second point with the same y-value.
The corresponding angle is pi minus the angle phi.
Beyond that, adding a full period (2pi) of the unit circle, will also yield the same y-values again.