An isomorphism means that the set of matrices behave the same way as the group.
Many groups have a trivial representation where you represent every group element by the identity matrix. The rules of the group multiplication table are satisfied. But one certainly doesn't learn anything interesting about the group by looking at these matrices!
An isomorphic (i.e., faithful) representation should have as many different matrices as there are group elements, and those matrices should obey the group's multiplication table.