Well, I am not exactly sure how to answer in a straightforward way, without talking about group theory. The charged leptons and their partner neutrinos are intimately connected, indeed before electroweak symmetry breaking they can be well considered to be two pieces of the same particle, or at least identical copies of each other (the charged leptons have no charge or mass before this occurs, and the neutrinos also have no mass, so they could not be distinguished from each other either). You can "mix" the two pieces together in various ways and the physics is unchanged, since this "doublet" is "symmetric under SU(2) transformations".
However, electroweak symmetry breaking occurs in such a way as to give half of the doublet electric charge and mass, but not the other half, thus distinguishing electrons from electron neutrinos, and so on. The "pairing" remains, however, and so during electroweak interactions electrons can "transform" into electron neutrinos by emitting or absorbing W bosons (and similarly for the other generations), and vice versa.
edit: Oh, weird, for some reason none of the other responses were visible to me before I posted this. Oh well.