Validity of the sudden approximation

In summary, the Schrodinger equation describes the time evolution of a physical state from ##t_0## to ##t##. By rewriting time as ##t=s\ T##, the equation can be simplified to ##i\ \frac{\partial}{\partial s}\ \mathcal{U}(t,t_{0})=\frac{H}{\hbar\ \Omega}\ \mathcal{U}(t,t_{0})##. In the sudden approximation, where ##T## approaches 0, ##\mathcal{U}(t,t_{0})## approaches 1 as ##t## approaches 0, proving the validity of the approximation. Redefining ##H## by adding or subtracting an arbitrary
  • #1
spaghetti3451
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Homework Statement



The Schrodinger equation is given by

$$i\hbar\ \frac{\partial}{\partial t}\ \mathcal{U}(t,t_{0})=H\ \mathcal{U}(t,t_{0}),$$

where ##\mathcal{U}(t,t_{0})## is the time evolution operator for evolution of some physical state ##|\psi\rangle## from ##t_0## to ##t##.Rewriting time ##t## as ##t=s\ T##, where ##s## is a dimensionless parameter and ##T## is a time scale, the Schrodinger equation becomes as

$$i\ \frac{\partial}{\partial s}\ \mathcal{U}(t,t_{0})=\frac{H}{\hbar/T}\ \mathcal{U}(t,t_{0})=\frac{H}{\hbar\ \Omega}\ \mathcal{U}(t,t_{0}),$$

where ##\Omega \equiv 1/T##.

In the sudden approximation, ##T \rightarrow 0##, which means that ##\hbar\ \Omega \gg H##. 1. Are we allowed to redefine ##H## by adding or subtracting an arbitrary constant?
2. How does this introduce some overall phase factor in the state vectors?
3. Why does this imply that ##\mathcal{U}(t,t_{0})\rightarrow 1## as ##t\rightarrow 0##?
4. How does this prove the validity of the sudden approximation?

Homework Equations



The Attempt at a Solution



1. I think that we are allowed to redfine ##H## by adding or subtracting an arbitrary constant, because ##H=T-V## and the potential ##V## can be redefined by adding or subtracting an arbitrary constant without changing the physical system.

What do you think?
 
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  • #2
Yes, you are allowed to redefine the Hamiltonian by addition of a constant. Note however that H=T+V, unless you are using an unusual definition of V.
You also have to take in mind that ##\hbar \Omega \gg H## is meaningless as you are comparing an operator with a number. As H usually is unbound, the sudden approximation never holds for all states and convergence is non-uniform.
 

What is the sudden approximation?

The sudden approximation is a theoretical concept used in physics and chemistry to simplify complex systems by assuming that certain reactions or processes happen instantaneously, without any intermediate steps.

Why is the sudden approximation used?

The sudden approximation is used in cases where the intermediate steps of a reaction or process are too difficult or time-consuming to measure or calculate accurately. It allows scientists to make simplifications and still obtain reasonable results.

What are the limitations of the sudden approximation?

The sudden approximation is only applicable in certain situations and may not accurately represent the true behavior of a system. It is also based on certain assumptions and may not hold true if those assumptions are not met.

How do scientists determine the validity of the sudden approximation?

Scientists can test the validity of the sudden approximation by comparing the results obtained using the approximation to those obtained through more detailed calculations or experiments. If the results are similar, the approximation is considered valid.

Are there alternatives to the sudden approximation?

Yes, there are other theoretical models and methods that can be used instead of the sudden approximation, such as the adiabatic approximation or the Born-Oppenheimer approximation. The choice of which method to use depends on the specific system and the level of accuracy required.

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