Voltmeter values drop w/ time when measuring elec chem cell?

In summary, the conversation revolved around a person setting up a zinc-copper electrochemical cell in lemon juice to test its conductivity. They used a voltmeter to measure the voltage over time and noticed a decrease in voltage. They asked for an explanation and were told that this is normal for homemade cells and that using copper sulfate solution would yield better results. The conversation also mentioned the potential toxicity of copper sulfate.
  • #1
mizzmarymary
2
0
I set up a zinc-copper elctrochemical cell by placing both electrodes in lemon juice to test the ability of lemon juice to conduct a current. I used a voltmeter and attached each lead to one of the metal electrodes. What I observed was that the voltage over time given on the voltmeter began to decrease and continued to decrease. I would be grateful if someone could explain what is happening? Thanks so much!
Mary
 
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  • #2
How long did the process take?
The voltmeter draws some current and the cell does not run forever.
 
  • #3
See "electrochemical cell polarization".
What you see is normal for these home made cells.
 
  • #4
nasu said:
See "electrochemical cell polarization".
What you see is normal for these home made cells.
These cells work better if you use copper sulfate solution instead of the lemon juice. Careful, it is toxic.
 

1. How do you measure the voltage of an electrochemical cell?

To measure the voltage of an electrochemical cell, you will need a voltmeter. Connect the positive lead of the voltmeter to the positive terminal of the cell and the negative lead to the negative terminal. The voltage reading on the voltmeter is the voltage of the cell.

2. Why do voltmeter values drop with time when measuring an electrochemical cell?

Voltmeter values drop with time when measuring an electrochemical cell because of the internal resistance of the cell. As the cell operates, the chemicals inside the cell are consumed, leading to a decrease in the voltage produced. This results in a drop in the voltmeter reading over time.

3. Is it normal for voltmeter values to fluctuate when measuring an electrochemical cell?

Yes, it is normal for voltmeter values to fluctuate when measuring an electrochemical cell. This is due to the constant chemical reactions happening inside the cell, which can cause minor changes in the voltage produced. These fluctuations are usually small and should not significantly affect the overall voltage reading.

4. How can you ensure accurate voltmeter readings when measuring an electrochemical cell?

To ensure accurate voltmeter readings when measuring an electrochemical cell, make sure to use a high-quality and calibrated voltmeter. Also, take multiple readings at different times and calculate an average to account for any fluctuations. It is also important to make sure the voltmeter leads are securely connected to the cell terminals to avoid any false readings.

5. Can you measure the voltage of an electrochemical cell without a voltmeter?

Yes, you can measure the voltage of an electrochemical cell without a voltmeter by using a multimeter set to the voltage measurement mode. However, the accuracy of the reading may be lower compared to using a voltmeter designed specifically for this purpose.

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