Volume work, absolute and relative pressure confusion

AI Thread Summary
The discussion revolves around the confusion between absolute pressure and atmospheric pressure in calculating work done by a gas in a cylinder with a piston. The user derived an equation for isothermal work but realized they neglected the negative work done by atmospheric pressure on the piston. They clarify that the work calculated reflects the gas's action on the piston, not the net work considering atmospheric pressure. To determine the total work obtainable from the piston, atmospheric pressure must be included in the calculations. This highlights the importance of accounting for all forces acting on the system when analyzing work in thermodynamic processes.
kandelabr
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hello.

i can't figure out where I'm wrong. this is the problem:

we have a cylinder, closed with a piston. the absolute pressure inside the cylinder is p0, atmospheric pressure is patm. the air inside expands isothermally to some (specific) volume vend.
i derived the equation for isothermal work directly from this one: dW = F(s)ds.

here it is (sorry for handwriting... uses less time :eek: (will learn TeX one day... :smile:)):
isotherm.jpg


the final equation seems just fine, but you've probably noticed the big fat asterisk. here's why:
p0 is absolute pressure and it exerts F(s0) on the piston. but there is also patm, which does negative work equal to patm * A * (send - s0). this fact hasn't been taken into account anywhere.

where am i wrong (the thermodynamics probably isn't wrong, right? :) )
 
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What you are calculating is the work done by the gas on the piston, not the net work done on the piston. The gas is not subjected to atmospheric pressure--it's contained in the cylinder.
 
oh, i get it.
but if now i want to know how much work i can get from this piston, i need to include atmospheric pressure.
 
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