What Causes the Change in Spin State from Fe(bipy)3 to Fe(bipy)2(H2O)2?

[silimay]

Why is Fe(bipy)3 low spin, whereas Fe(bipy)2(H2O) high spin?

 

[Borek]

Common, that's the most basic question, it must be covered in your book. Start with a general question - why are some complexes high spin whereas others are low spin? What does the spin tell about the d orbitals in the complexed metal?

 

[chemisttree]

The real question is, "Why does the addition of 2 water ligands change the value of 10Dq so much?"