What is the atomic spacing D of this crystal?

In summary, the conversation discusses the use of X-rays with a wavelength of 0.10 nm to determine the atomic spacing of a crystal with a hexagonal structure. The Bragg condition is used to determine the distance between crystal planes, which is then used to calculate the atomic spacing of the crystal.
  • #1
spaghed87
24
1

Homework Statement


X rays with wavelength 0.10 nm are incident on a crystal with a hexagonal crystal structure. The x-ray diffraction spectrum is shown in the figure.

Figure:
knight_Figure_24_40.jpg




What is the atomic spacing D of this crystal? (in nanometers)



Homework Equations



The Bragg condition:
2*D*cos(theta)=m*lamda where, m=1,2,3...


The Attempt at a Solution



(m+1)/(m) ==> cos(50.1)/cos(71.3) = (2/1)

(m+1)/(m)==> cos(15.8)/cos(71.3) = (3/1)

D=(2*lamda)/(2*cos(theta_2)==> (lamda)/cos(theta_2)==> (0.10nm)/cos(50.1)=0.16nm

I just followed a similair example in the book. Maybe I'm getting it wrong because I'm not factoring anything in about the hexagonal shape in my math? *Note: this is a challange problem.
 
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  • #2
(Note to others: OP is using ##\theta## defined relative to the normal of the plane, rather than parallel, hence the appearance of the cosine rather than the more usual sine in the Bragg condition.)

OP, you have correctly determined that the distance between the crystal planes is 0.16 nm. However, the problem is looking for the distance between atoms, so you’ll need to use the crystal geometry to solve for D.
 
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1. What is atomic spacing D?

Atomic spacing D refers to the distance between adjacent atoms in a crystal lattice structure. It is a measure of the regularity and stability of the crystal's arrangement of atoms.

2. How is atomic spacing D measured?

Atomic spacing D can be measured using various techniques such as X-ray diffraction, electron diffraction, and atomic force microscopy. These methods involve analyzing the scattering or interference patterns of waves passing through the crystal lattice.

3. What factors can affect atomic spacing D?

Atomic spacing D can be affected by temperature, pressure, and the type of atoms present in the crystal. Changes in these factors can cause the atoms to vibrate or move, resulting in a change in the distance between them.

4. What is the significance of knowing atomic spacing D?

Knowing atomic spacing D is essential in understanding the physical and chemical properties of a crystal. It can also provide insight into the behavior of materials under different conditions and aid in the design of new materials with specific properties.

5. Can atomic spacing D be altered?

Yes, atomic spacing D can be altered by introducing defects or impurities into the crystal lattice, changing the temperature or pressure, or by applying an external force. These alterations can affect the properties and behavior of the crystal.

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