The effective electromotive force (emf) of two cells connected in parallel with zero internal resistance is determined by their individual emfs. If both cells have equal emfs, the effective emf remains the same as that of either cell. In cases where the cells have different emfs, the effective emf is equal to the higher emf. The discussion emphasizes that all cells inherently possess internal resistance, making division-by-zero scenarios impractical. Therefore, for two cells in parallel, the effective emf is simply the greater of the two.