The discussion centers on the heat of formation of water vapor at standard temperature and pressure. The heat of formation for H2O from hydrogen and oxygen is noted as -68.32 Kcal/Mol. Additionally, the latent heat of evaporation is mentioned as -600 cal/g, while the heat of formation for a mole of water vapor is specified as -241.82 kJ. There is some confusion regarding the phrase "at standard temperature," and participants clarify that the heat of formation for water vapor is indeed -241.8 kJ/mol, aligning with previous answers provided in the thread.