What is the impact of temperature on the rate of the reaction at 45C?

  • Thread starter Thread starter Saterial
  • Start date Start date
  • Tags Tags
    Reaction
AI Thread Summary
The discussion focuses on calculating the rate constant for the reaction C12H22O11 + H2O at 45°C, given the rate constant at 35°C and the activation energy of 108 kJ/mol. The Arrhenius equation is used to relate temperature changes to the rate constant, with a suggestion to convert temperatures to Kelvin for accuracy. Participants clarify that the impact on the rate refers to how the rate constant changes with temperature, emphasizing the importance of using the correct parameters in calculations. There is also a note that the change in temperature does not affect the method of calculation. The conversation highlights the need for careful application of the Arrhenius equation to determine the rate constant accurately.
Saterial
Messages
54
Reaction score
0

Homework Statement


At 35C, the rate constant for the reaction: C12H22O11 + H20 --> C6H12O6 + C6H12O6 is k=6.2 x 10^-5 s-1. The activation energy for the reaction is 108 kJ/mol. What is the rate constant for the reaction at 45C? Determine the impact on the rate.


Homework Equations


r=Ae^-Ae/RT
r=k[C12H22O11][H2O]

The Attempt at a Solution



I don't know if I am even using the right equation, (Arrhenius equation) however I tried seperating the reaction into 35C and 45C stages and analyzed from there. At 35C, Ae is given so I plugged the Ae into the Arrhenius eq at 45C and cancel out the A base as it is the same at both 35C and 45C.

Ended up with :
r=e^(-108000/8.314*10). (change in temp of 10C)

Does this make any sense or even work? If so, what does the second part of impact on the rate mean?

Thanks a bunch.
 
Physics news on Phys.org
What you found is ratio of rates, not rate. Use data for 35 deg C to find A, then just plug and chug for 45 deg C.
 
Also, given that the constant is given by J/Mol K, I would have thought you were supposed to use Kelvins instead of degrees Celsius.
 
When it comes to delta T it doesn't matter. A lot depends on how Saterial got to the expression shown.
 
Borek said:
When it comes to delta T it doesn't matter. A lot depends on how Saterial got to the expression shown.

Ah. Missed we were using delta.
 
Thread 'Confusion regarding a chemical kinetics problem'
TL;DR Summary: cannot find out error in solution proposed. [![question with rate laws][1]][1] Now the rate law for the reaction (i.e reaction rate) can be written as: $$ R= k[N_2O_5] $$ my main question is, WHAT is this reaction equal to? what I mean here is, whether $$k[N_2O_5]= -d[N_2O_5]/dt$$ or is it $$k[N_2O_5]= -1/2 \frac{d}{dt} [N_2O_5] $$ ? The latter seems to be more apt, as the reaction rate must be -1/2 (disappearance rate of N2O5), which adheres to the stoichiometry of the...
I don't get how to argue it. i can prove: evolution is the ability to adapt, whether it's progression or regression from some point of view, so if evolution is not constant then animal generations couldn`t stay alive for a big amount of time because when climate is changing this generations die. but they dont. so evolution is constant. but its not an argument, right? how to fing arguments when i only prove it.. analytically, i guess it called that (this is indirectly related to biology, im...
Back
Top