What is the lowest rotational energy level for a diatomic molecule?

Join the discussion
Registration is free. Start your own thread to ask a follow-up.
2 replies · 2K views
spaghetti3451
Messages
1,311
Reaction score
31
My book on Physics by Beiser specifies that the rotational energy levels of a diatomic molecule are given by J(J+1)/ℏ2, where J = 0, 1, 2, 3, ... .

However, in the next page, it goes on to mention that the lowest rotational energy level corresponds to J = 1.

I don't see why that shouldn't be J = 0.

Any comments would be greatly appreciated.
 
Physics news on Phys.org
Let me rephrase my question.

I know that the rotational quantum number starts at J = 0,

but do you count the lowest rotational energy state as J = 0 or as J = 1?