Write down the "operation table" for the group. Let's say that "e" is the identity and you have elements a, b, etc. Notice that multiplying a by each member of the group gives the row labled "a" on your operation table. Each of the members of the group appears once and only once on that row. That is, the row is a "permutation" of the top row just listing the elements of the group. If you replace e, a, b, etc. with 0, 1, 2, etc. each row is a permutation of {0,1,2, ...}. That is the permutation representation.
Take, for example, the Klein 4-group. Its operation table is
__e a b c
e e a b c
a a e c b
b b c e a
c c b a e
Now replace those with 0, 1, 2, 3 and the table is
__0 1 2 3
0 0 1 2 3
1 1 0 3 2
2 2 3 0 1
3 3 2 1 0
That is, 0, the identity, takes {0, 1, 2, 3} to {0, 1, 2, 3}, the identity permutation.
1 takes {0, 1, 2, 3} to {1, 0, 3, 2}, the permutation (0 1)(2 3)
2 takes {0, 1, 2, 3} to {2, 3, 0, 1}, the permutation (0 2)(1 3)
3 takes {0, 1, 2, 3} to {3, 2, 1, 0}, the permutation (0 3)(1 2).
Those four permutations (out of 4!= 24 possible permutations of {0, 1, 2, 3}) are the permutation representations of the elements of the Klein 4-group.