Sturm and Liouville in the nineteenth century introduced the technology of linear algebra into the theory of differential equations and showed the importance of eigenvalues to the solutions. This mathematical technology, as subsequently developed by Hilbert and others, is the basis for solutions in quantum theory.
#3
QMrocks
85
0
Thanks! i was curious if understanding of this Sturm and Liouville theory is pertinent to the understanding of QM and what essence would one miss if one does not know this this...
#4
snooper007
33
1
In QM, completeness of eigenfunctions is very important, the completeness
in Sturm and Liouville theory is also very important.
I would like to know how to calculate the ##[\hat{H}, \hat{P}]## for a particle in a 1D box? At the first glance it seems that they commute but they don't get diagonalized in identical basis. How to calculate this commutation?
I don't know why the electrons in atoms are considered in the orbitals while they could be in sates which are superpositions of these orbitals? If electrons are in the superposition of these orbitals their energy expectation value is also constant, and the atom seems to be stable!