Undergrad What is this notation D|(n;n')|, and how to solve it?

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SUMMARY

The discussion centers on the notation D|(n;n')|, which is essential for calculating the intensity distribution of the doublet state in diatomic molecules as described in E. Hill's paper. This notation encompasses transitions in vibrational and electronic quantum numbers, with 'n' representing the totality of these quantum numbers. Participants emphasize the importance of understanding Hill's work, despite the availability of more modern resources like Herzberg's "Spectra of Diatomic Molecules" and Bransden and Joachain's "Physics of Atoms and Molecules." The conversation highlights the historical context of quantum mechanics while advocating for a focus on contemporary interpretations.

PREREQUISITES
  • Understanding of quantum mechanics fundamentals
  • Familiarity with diatomic molecular spectra
  • Knowledge of vibrational and electronic quantum numbers
  • Basic linear algebra concepts
NEXT STEPS
  • Study E. Hill's paper on intensity calculations for diatomic molecules
  • Explore Herzberg's "Spectra of Diatomic Molecules" for modern insights
  • Review Bransden and Joachain's "Physics of Atoms and Molecules" for foundational concepts
  • Investigate the implications of historical perspectives in quantum mechanics
USEFUL FOR

Students and researchers in quantum mechanics, particularly those focused on diatomic molecules and their spectral properties, as well as anyone interested in the historical development of quantum theory.

K-Manu
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TL;DR
Meaning of the notation for calculating the intensity of diatomic molecules.
I'm a beginner in the quantum mechanic and reading E. hill's paper explaining the intensity distribution of the doublet state for diatomic molecule (D->P).
To calculate the intensities, D|(n;n')| and/or q(n,a,j;n'a',j') must be calculated, but I have never seen it before in linear algebra/quantum mechanics.
What is the notation meaning, and how to calculate it?

*D|(n;n')| is suggested to include transitions in the vibrational and electronic quantum number and n is the totality of the quantum number as mentioned in the paper.Reference
1) https://journals.aps.org/pr/abstract/10.1103/PhysRev.32.250
2) https://www.pnas.org/doi/pdf/10.1073/pnas.15.10.779
 
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These papers are from 1928 and 1929. The knowledge of the spectra of diatomic molecules has evolved a lot since then. I suggest you look at more recent resources: Herzberg's Spectra of Diatomic Molecules from 1950 is already much more modern. Another good reference is Bransden and Joachain, Physics of Atoms and Molecules.
 
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DrClaude said:
These papers are from 1928 and 1929. The knowledge of the spectra of diatomic molecules has evolved a lot since then. I suggest you look at more recent resources: Herzberg's Spectra of Diatomic Molecules from 1950 is already much more modern. Another good reference is Bransden and Joachain, Physics of Atoms and Molecules.
I read the books which you recommanded.
But, E. Hill is who found the ways to calculate the intensities of diatomic molecules.
Thus, I need to understand his paper, not other.
Thank you for answer.
 
K-Manu said:
But, E. Hill is who found the ways to calculate the intensities of diatomic molecules.
Thus, I need to understand his paper, not other.
Why? What is your end game? If it is to write a book about the historical development of this area of science, then okay. But if you are trying to understand reality as understood today, why would you burn so many of your intellectual cycles with old perspectives?
 
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Time reversal invariant Hamiltonians must satisfy ##[H,\Theta]=0## where ##\Theta## is time reversal operator. However, in some texts (for example see Many-body Quantum Theory in Condensed Matter Physics an introduction, HENRIK BRUUS and KARSTEN FLENSBERG, Corrected version: 14 January 2016, section 7.1.4) the time reversal invariant condition is introduced as ##H=H^*##. How these two conditions are identical?

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