Metal surfaces do not exhibit visible diffraction patterns due to their atomic structure and the presence of free electrons, which create a barrier that prevents light waves from interacting with the atomic grating. The complex refractive index of metals, with its imaginary component, accounts for the absorption and reflection of electromagnetic waves, further obscuring diffraction effects. In contrast, dielectrics, which lack free electrons, can show diffraction patterns since their atomic spacing is suitable for visible wavelengths. However, X-rays and gamma rays can penetrate metal surfaces and interact with the atomic structure, allowing for diffraction to occur in these cases. Thus, while visible light cannot diffract off metals, higher energy electromagnetic radiation can reveal their crystalline properties.