cube137 said:
Why is the off-diagonal terms not that important when you can tell from it whether it's pure or mixed state? And for a pure state, can you say the off-diagonal term has value of 100%?
If you're going to dig as deeply into the formalism as you want to, you're going to have to learn the math - there is no other way to get to where you want to be. Atyy's link is very good, but it is written for people who have already been through a no-kidding college-level introduction to quantum mechanics, where the basic notion of states as vectors in a Hilbert space is taught. Only after you've been through that will you be ready to take on the density matrix formalism.
But a quick answer to why the off-diagonal terms don't matter is that you can make them disappear just by changing the basis. As an exercise, you might try writing the density matrices for the following states, using the spin-up/spin-down and spin-left/spin-right bases so you write the density matrix in two different forms for each case:
1) A spin-1/2 particle has been prepared in the spin-up state by selecting it from the upwards-deflected beam of a vertically oriented Stern-Gerlach device.
2) A spin-1/2 particle has been prepared in the spin-left state by selecting it from the leftwards-deflected beam of a horizontally oriented Stern-Gerlach device.
3) A spin-1/2 particle has been randomly selected from one of the two beams coming out of a vertically-oriented Stern-Gerlach device.
4) A spin-1/2 particle has been randomly selected from one of the two beams coming out of horizontally-oriented Stern-Gerlach device.
#1 and #2 are pure states. #3 and #4 are mixed states. #1 is a superposition when written in the left/right basis but not when written in the up/down basis; #2 is the other way around. All four of these states will have off-diagonal elements in one basis or the other.