What's confusing? You're writing it as a vector space, and writing down a map. You're asked to show it is a ring homomorphism too. It wouldn't be the way I'd do it (though it is equivalent).If you know these are fields, it suffices to count elements. If you don't then you need to write down a ring homomorphism, so you need to get your hands dirty and do it. Any ring map sends 1 to 1, and must send x to ax+b for some choice of a and b. So figure out what, if any, choices of a and b mean this is an isomorphism.
There are only two things to remember: 2=-3 mod 5 (why do I keep writing that I wonder...) and 4=-1 mod 5 (that is the second hint).