What is the difference between a dipole and polarity?

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A dipole in chemistry refers to the separation of electric charges within a molecule, typically between two covalently bonded atoms with differing electronegativities. This separation results in a dipole moment, which quantifies the polarity of the molecule. Polarization, on the other hand, involves changes in the dipole moment due to an external electric field or the distribution of electric fields within a medium. It can be viewed as the density of dipole moments across a material. The discussion highlights the complexity of these concepts, particularly the mathematical aspect of dipole definitions through multipole expansion, which may be challenging for those less familiar with advanced chemistry and mathematics. Simplifying these ideas could help in understanding the relationship between dipoles and polarization in a more accessible manner.
marc32123
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From what I have been learning recently, a dipole is a separation of electric charges and in chemistry, a dipole refers to the separation of charges within a molecule between two covalently bonded atoms (which is caused from one atom having a higher electronegativity) What I don't understand is how this is different from polarization in chemistry?
 
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A dipole is defined more strictly via a multipole expansion of the charge contribution, see
http://en.wikipedia.org/wiki/Multipole_expansion
Polarisation referseither to a change of the dipole moment due to an external field or to the sources of the electric field inside the medium. In simple situations, the latter can be interpreted as the macroscopic dipole moment density.
 
Thanks for the info, although it is kind of out of the realm of what I understand about chem so far. I checked out that article on wiki already and had no idea what it was saying. I am terrible with math. Is there any way you could somewhat explain it in a somewhat understandable way what you mean by

A dipole is defined more strictly via a multipole expansion of the charge contribution

It would be greatly appreciated!
 
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