What Determines the Presence of a P-Orbital in an Atom's Electron Configuration?

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The discussion centers on the requirements for populating p-orbitals in atomic structures, specifically using lithium as an example. Lithium has the electron configuration of 1s2, 2s1, indicating that it has one electron in the 2s orbital. To begin filling a p-orbital, at least two additional electrons are needed, which would result in a hypothetical Li-2 configuration. However, lithium typically prefers to lose its single 2s electron rather than gain more, making the filling of a p-orbital challenging but not entirely impossible.
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Hi,

I understand that there are various types of orbitals (s, p, d, f, etc.) If we take Lithium for example, its electron configuration would be 1s2, 2s1. What would be the requirements for there to be a p-orbital? Does it have to do with the number of electrons?

Thanks,
 
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Yes. For you start populating a p orbital for lithium you need to add at least two additional electrons to make Li-2 when all it really wants to do is just lose one. Very difficult to do but perhaps not impossible.
 
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