Fermi Level Explained: What is It?

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    Fermi Fermi level
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Discussion Overview

The discussion revolves around the concept of the Fermi level, exploring its definition, significance, and variations in interpretation across different contexts, particularly in solid state physics and semiconductor theory.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • Some participants define the Fermi level as the lowest energy level for a system of fermions, while others suggest it is more accurately described as the energy level where the probability of finding a fermion is 50%.
  • One participant presents the Fermi level as the temperature-dependent chemical potential of a fermionic substance, relating it to the Fermi-Dirac distribution and the filling of orbitals.
  • Another participant argues that the Fermi level is the highest energy of the valence electronic band at absolute zero temperature for semiconductors, while for conductors, it is the highest energy of conduction electrons in the conduction band.
  • There is mention of confusion arising from the mixing of the chemical potential with the Fermi level, highlighting that definitions can vary based on the field of study and literature.
  • One participant references a textbook to support their definition of the Fermi level, indicating that interpretations may depend on the context and the specific field of solid state physics.

Areas of Agreement / Disagreement

Participants express differing views on the definition and implications of the Fermi level, indicating that multiple competing interpretations exist without a clear consensus.

Contextual Notes

Some definitions presented may depend on specific contexts, such as solid state physics versus semiconductor theory, and there are unresolved nuances regarding the relationship between the Fermi level and chemical potential.

Mk
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Hey, guys, what's a fermi level?
 
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It's the lowest energy level for a system of fermions.

or... that would be the fermi energy...
 
Galileo said:
It's the lowest energy level for a system of fermions.

or... that would be the fermi energy...

Maybe the level away from fermi-energy? If zero-point energy is the lowest energy, why do fermions have a higher fermi energy?
 
Think it's the energy level where the probability of finding a fermion for a system of fermions is 50%...
 
The Fermi level is the temperature dependent 'chemical potential' of a fermionic substance. It is also the energy at which an obital is exactly half filled. This can be seen from the Fermi-Dirac distribution:

[tex]f(\epsilon)=\frac{1}{e^{(\epsilon-\mu(\tau))/\tau}-1}[/tex]

Where [itex]\tau[/itex] is the fundamental temperature [itex]k_BT[/itex], [itex]\epsilon[/itex] the energy of the orbital and [itex]\mu[/itex] the chemical potential or fermi level. This gives the probabality of finding a particle in an orbital with energy epsilon, it is also the expectation value of fermions in that orbital because there can be only 1 or 0 fermions in an orbital because of the Pauli exclusion principle. If you fill in [itex]\epsilon=\mu[/itex] this yields 1/2.

So for energies below the fermi level orbitals are more than half filled and above they are less than half filled. The Fermi energy is the fermi level at absolute zero temperature.

[tex]\epsilon_{F}=\mu(0)[/tex]
 
da_willem said:
The Fermi level is the temperature dependent 'chemical potential' of a fermionic substance. It is also the energy at which an obital is exactly half filled. This can be seen from the Fermi-Dirac distribution:

[tex]f(\epsilon)=\frac{1}{e^{(\epsilon-\mu(\tau))/\tau}-1}[/tex]

Where [itex]\tau[/itex] is the fundamental temperature [itex]k_BT[/itex], [itex]\epsilon[/itex] the energy of the orbital and [itex]\mu[/itex] the chemical potential or fermi level. This gives the probabality of finding a particle in an orbital with energy epsilon, it is also the expectation value of fermions in that orbital because there can be only 1 or 0 fermions in an orbital because of the Pauli exclusion principle. If you fill in [itex]\epsilon=\mu[/itex] this yields 1/2.

So for energies below the fermi level orbitals are more than half filled and above they are less than half filled. The Fermi energy is the fermi level at absolute zero temperature.

[tex]\epsilon_{F}=\mu(0)[/tex]

Er... I think what you are describing is more appropriate for a semiconductor system.

A "fermi level" is the highest energy of the valence electronic band at T=0 K.

For a conductor, the fermi level is the highest energy of the conduction electron in the conduction band. For an intrinsic semiconductor, at T=0 K, it is technically the top of the filled valence band, since the conduction band is completely empty. However, there are many books and people who mix and match the chemical potential that is in the middle of the band gap with the Fermi level. This is where it can create confusion as to what a "fermi level" actually means.

http://edu.ioffe.ru/register/?doc=galperin/l4pdf2.tex

Zz.
 
Last edited by a moderator:
ZapperZ said:
However, there are many books and people who mix and match the chemical potential that is in the middle of the band gap with the Fermi level. This is where it can create confusion as to what a "fermi level" actually means.

http://edu.ioffe.ru/register/?doc=galperin/l4pdf2.tex

Zz.

Im now studying for my thermal physics test on monday and what I wrote in my previous post can be found in "Thermal physics" by Kittel and Kroemer. They say the definition I gave of the Fermi level is "often used in the field of solid state physics". So I guess wou're right when you say the meaning of the Fermi-level depends on the field and the book you're reading...
 
Last edited by a moderator:
da_willem said:
Im now studying for my thermal physics test on monday and what I wrote in my previous post can be found in "Thermal physics" by Kittel and Kroemer. They say the definition I gave of the Fermi level is "often used in the field of solid state physics". So I guess wou're right when you say the meaning of the Fermi-level depends on the field and the book you're reading...

And in case you don't know, Kittel also wrote a solid state physics text. :)

Zz.
 

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