It's now years since I studied this, if anyone could help me remember.
If I look at a hydrogen atom and it's shells. In the ground state there's 1s, the wave function is then:
\Psi_{nlm}(r,\theta,\phi) = Y_{lm}(\theta,\phi)R_{nl}(r) = Y_{00}R_{10}
Y_{00} = \frac{1}{\sqrt{4\pi}}
R_{10}...