Accidental Hydrogen Production from Gallium and Aluminium Oxide

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Discussion Overview

The discussion revolves around the accidental production of hydrogen gas when gallium is combined with aluminum oxide and water. Participants explore the underlying chemical reactions and compare them to other metal reactions, particularly in acidic conditions.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant notes that aluminum is typically reactive but is protected by a stable oxide layer, which can be disrupted in acidic or basic conditions, allowing for reactions that produce hydrogen.
  • Another participant draws a parallel to the aluminum and mercury reaction, suggesting that gallium prevents the formation of the oxide layer, facilitating the reaction with water.
  • A question is posed about the potential for iron to react with hydrochloric acid to produce hydrogen, with a follow-up confirming that iron is indeed the English equivalent of ferum.
  • It is mentioned that zinc is also a good metal for producing hydrogen in similar reactions.

Areas of Agreement / Disagreement

Participants express varying degrees of agreement on the reactivity of aluminum and gallium, but the discussion about iron and hydrochloric acid introduces a new line of inquiry that remains unresolved.

Contextual Notes

Some assumptions about the conditions under which aluminum reacts with water and the role of the oxide layer are not fully explored. The discussion also does not clarify the specific conditions required for the reactions mentioned.

Who May Find This Useful

Individuals interested in chemical reactions involving metals, particularly in the context of hydrogen production, may find this discussion relevant.

bioman06
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Hi guys

I was looking at a website and the engineer was working with Gallium and Allaminium oxide, and by accident they put water with it and the reaction produced hydrogen.

Could anyone expand on this?

regards
Bioman
 
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No surprise here, aluminum is very reactive. It is just almost always covered with very stable oxide, which makes it water resistant, as long as water is neutral (pH around 7). When it is acidic or basic oxide dissolves and aluminum reacts. Gallium doesn't allow oxide layer creation.

To some extent that's similar to the famous aluminum and mercury experiment, in which aluminum gets oxidized fast when small amount of mercury is put on its surface. That's why you are not allowed to carry mercury on bard of passenger planes.

This is an old news now, it hit the headlines last year.
 
To produce Hydrogen, can I put a metal such as Ferum into Hydrochloric Acid and get Hydrogen? I think Ferum and Hydrochloric Acid will react and produce Ferum Chloride and Hydrogen.
 
I am assuming that iron is the English equivalent of ferum.

I believe the answer to your question is, yes.

IIRC zinc is a good metal for this as well.
 

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