Adhesion of Al and Au: Investigating the Bond

  • Thread starter Thread starter Si14
  • Start date Start date
  • Tags Tags
    Adhesion Bond
AI Thread Summary
The discussion centers on the adhesion challenges when depositing gold (Au) on aluminum (Al), highlighting that adhesion is generally poor and can lead to intermetallic formation, specifically referencing the "purple plague" phenomenon. To enhance adhesion and mitigate these issues, it is recommended to deposit a titanium (Ti) or titanium/tungsten (Ti/W) layer between the Al and Au. A Ti layer of approximately 20nm is suggested as sufficient for improving adhesion in this context.
Si14
Messages
75
Reaction score
0
Dear all:

I wonder how the adhesion between Al and Au is. I am going to deposit Au on top of Al layer.

Regards.
 
Chemistry news on Phys.org
The adhesion is not that good. In addition, there is a problem of intermetallic formation (look up "purple plague" on Wikipedia) that can cause problems. For this reason, in my past experience we deposited a Ti or Ti/W layer between the Al and the Au to improve adhesion and prevent intermetallic formation.
 
Great hint. I am going to deposit about 200nm Au on Al layer. So you think it's better to deposit Ti between them? How thick this layer should be? 20nm is fine?

Thank again.
 
Yes, I think the Ti layer would be a good idea. 20nm should be thick enough.
 
It seems like a simple enough question: what is the solubility of epsom salt in water at 20°C? A graph or table showing how it varies with temperature would be a bonus. But upon searching the internet I have been unable to determine this with confidence. Wikipedia gives the value of 113g/100ml. But other sources disagree and I can't find a definitive source for the information. I even asked chatgpt but it couldn't be sure either. I thought, naively, that this would be easy to look up without...
I was introduced to the Octet Rule recently and make me wonder, why does 8 valence electrons or a full p orbital always make an element inert? What is so special with a full p orbital? Like take Calcium for an example, its outer orbital is filled but its only the s orbital thats filled so its still reactive not so much as the Alkaline metals but still pretty reactive. Can someone explain it to me? Thanks!!
Back
Top