Adiabatic Irreversible Process

In summary, there is often disagreement on the determination of entropy in an irreversible adiabatic process. The Clausius inequality states that an irreversible adiabatic expansion will increase the entropy of a system. This is further supported by the fact that the total entropy of an isolated system or the universe increases during such a process. However, there is confusion regarding the concept of spontaneity and how it relates to the change in entropy. It is possible for the entropy of the system to decrease, but the entropy of the environment will increase by a greater amount in an irreversible process.
  • #1
Brian Curtis
2
0
Why does there tend to be disagreement on an irreversible adiabat entropy determination? Doesn't an irreversible adiabatic expansion increase the entropy of a system by the Clausius inequality?
 
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  • #2
Total entropy of an isolated system or of Universe increases when the isolated system or universe undergoes irreversible adiabatic process.
 
  • #3
Let'sthink said:
Total entropy of an isolated system or of Universe increases when the isolated system or universe undergoes irreversible adiabatic process.
That's what I've thought. It can be proved by determining entropy through a reversible cycle. However, in class, it was mentioned on an assignment that the delta S is negative and not spontaneous. Which again, does not make sense
 
  • #4
I do not understand what is meant by spontaneous but for any process the change in entropy of a system can be negative but then the change in entropy of environment will be positive and greater in magnitude of the change for system, for an irreversible process.
 

1. What is an adiabatic irreversible process?

An adiabatic irreversible process is a thermodynamic process that occurs without any heat exchange with the surroundings, and is not reversible. This means that the system's entropy increases during the process, and it cannot return to its initial state without external intervention.

2. How is an adiabatic irreversible process different from an adiabatic reversible process?

In an adiabatic reversible process, the system is able to return to its initial state without any change in entropy. This is because the process is carried out slowly, allowing the system to maintain thermodynamic equilibrium at all times. In contrast, an adiabatic irreversible process occurs quickly and does not allow the system to reach equilibrium, resulting in an increase in entropy.

3. What are some examples of adiabatic irreversible processes?

Some common examples of adiabatic irreversible processes include free expansion of a gas into a vacuum, sudden compression of a gas, and mixing of two gases without thermal contact. These processes occur quickly and do not allow the system to reach equilibrium, resulting in an increase in entropy.

4. How does an adiabatic irreversible process affect the internal energy of a system?

During an adiabatic irreversible process, the internal energy of a system may change due to work being done on or by the system. However, there is no heat transfer involved, so the change in internal energy is solely due to work. The change in internal energy can be calculated using the first law of thermodynamics, which states that the change in internal energy is equal to the work done on or by the system.

5. Can an adiabatic irreversible process be reversed?

No, an adiabatic irreversible process cannot be reversed. This is because the process occurs quickly and does not allow the system to reach equilibrium, resulting in an increase in entropy. In order to reverse the process, external intervention would be required to decrease the system's entropy, which goes against the second law of thermodynamics.

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