What causes the difference in reactivity between alkali metals?

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In summary, the reactivity between lithium, sodium, and potassium is due to their exposure to air, while rubidium and cesium catch fire. This is because the ions get bigger and the ionization energies become smaller as you go down the periodic system, making it easier for the bigger elements to start a reaction. The difference in behavior between rubidium and potassium is simply a matter of reaching a threshold in the rate of energy release.
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Calpalned
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We know that lithium, sodium and potassium tarnish when exposed to air, but rubidium and cesium catch on fire. Why is there such a huge jump in reactivity between Rb and K?
 
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Good question. Because going down in the periodic system, the ions get bigger and bigger, ionization energies become smaller. So it's easier to start a reaction with the bigger guys.
Does that make it clearer ?
 
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BvU has it right. There's not really a "huge jump" in reactivity ... it's just a matter of reaching a threshold in the rate of energy release, to a point where things proceed differently. Expose K to hot air, or to a higher concentration of oxygen, and it will behave like Rb.
 
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1. What are the properties of alkali metals that make them highly reactive?

Alkali metals are highly reactive due to their low ionization energy, which allows them to readily lose electrons and form positive ions. They also have a low electronegativity and high atomic radius, making it easy for them to bond with other elements.

2. How do alkali metals react with water?

Alkali metals react vigorously with water, producing hydrogen gas and a strong base. This is because they have a strong tendency to donate their outermost electron, forming a positively charged ion that reacts with the water molecules.

3. Why do alkali metals become more reactive as you move down the group?

As you move down the group, the atomic radius of alkali metals increases, making it easier for them to lose their outermost electron. This is due to the shielding effect of inner electrons, which reduces the attraction between the outermost electron and the nucleus.

4. What is the most reactive alkali metal?

The most reactive alkali metal is francium, which is located at the bottom of the group. It has the largest atomic radius and the lowest ionization energy, making it the most likely to lose its outermost electron.

5. How do alkali metals react with halogens?

Alkali metals react with halogens, such as chlorine and fluorine, to form ionic compounds. The alkali metal donates its outermost electron to the halogen, forming a positively charged ion, while the halogen accepts the electron, forming a negatively charged ion. These compounds are highly reactive and can be explosive.

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