Balancing Chemical Equations: Considering States of Reactants and Products

  • Thread starter Thread starter campa
  • Start date Start date
AI Thread Summary
The discussion centers around the chemical equation 2NH3(s) + 3Cl2(g) -> N2(g) + 6HCl(g), specifically questioning the state of ammonia (NH3). At standard temperature and pressure (STP), ammonia is typically a gas, although it is often encountered in aqueous solution in laboratory settings. Participants suggest that the notation NH3(s) may be incorrect, proposing that it should be NH3(aq) or NH3(g) instead, especially since NH3 in solid form would not align with common laboratory practices. The conversation also touches on the potential formation of nitrogen trichloride (NCl3) when ammonia reacts with excess chlorine gas, highlighting the explosive nature of NCl3. Additionally, the formation of ammonium chloride (NH4Cl) is mentioned, particularly in reactions involving excess ammonia. Overall, the consensus leans towards the idea that the original equation likely contains a misprint regarding the state of ammonia.
campa
Messages
33
Reaction score
0
2NH3(s) + 3Cl2(g) -> N2(g) + 6HCl(g)

What should the state of NH3 be?
 
Chemistry news on Phys.org
NH3(s) ? What temperature are you working at ?
 
Borek said:
At STP ammonia is a gas, although in lab practice it is most commonly used as a water solution.


Borek

Yeah, my thought was that he was talking about NH3(aq) (which is NH4OH), not the solid. Which of course produces (with Cl2(g)) NCl3 a moderate explosive. Hey haven't we all played with NI3 ... the stories I could tell ;)
 
Last edited:
the equation was given to us like 2NH3(s) + 3Cl2(g) -> N2(g) + 6HCl(g) I'm not sure about the temperature though. And it also said that with extra Cl2 you get the equation like Cl2(g)+NH3(g) -> NCl3(g) + HCl(g)
I suppose the state of NH3 in the first equation must be gas. The teacher must have misprinted it!
 
campa said:
the equation was given to us like 2NH3(s) + 3Cl2(g) -> N2(g) + 6HCl(g) I'm not sure about the temperature though. And it also said that with extra Cl2 you get the equation like Cl2(g)+NH3(g) -> NCl3(g) + HCl(g)
I suppose the state of NH3 in the first equation must be gas. The teacher must have misprinted it!

Close but one of the products from the gas phase reaction is NH4Cl(s).
 
but I thought that you get NH4Cl(s) when you use extra NH3
 
campa said:
but I thought that you get NH4Cl(s) when you use extra NH3

Another hint: H2(g).
 
Back
Top